Modification of the Upper Rim of Homooxacalix[3]arenes and Complexation between a Nitrohomooxacalix[3]arene Derivative and n-Hexylamine

Modification of the Upper Rim of Homooxacalix[3]arenes and Complexation between a Nitrohomooxacalix[3]arene Derivative and n-Hexylamine

Several functional groups were introduced on the upper rim of (lower rim free) homooxacalix[3]arene for the first time. The swinging nitrohomooxacalix[3]arene host 1 was fixed in the cone conformation by complexation with n-hexylamine.

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Veröffentlicht in:Journal of organic chemistry 2002-11, Vol.67 (23), p.8151-8156
Hauptverfasser: Tsubaki, Kazunori, Otsubo, Tadamune, Morimoto, Tatsuya, Maruoka, Hiromi, Furukawa, Mika, Momose, Yashima, Shang, Muhong, Fuji, Kaoru
Format: Artikel
Sprache:eng
Schlagworte:
Amines - chemistry
Chemistry
Crystallography, X-Ray
Ethers, Cyclic - chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Magnetic Resonance Spectroscopy
Molecular Structure
Nitrophenols - chemistry
Organic chemistry
Preparations and properties
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Zusammenfassung:Several functional groups were introduced on the upper rim of (lower rim free) homooxacalix[3]arene for the first time. The swinging nitrohomooxacalix[3]arene host 1 was fixed in the cone conformation by complexation with n-hexylamine.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo026152p