Towards Main-Chain-Polyoxometalate-Containing Hybrid Polymers: A Highly Efficient Approach to Bifunctionalized Organoimido Derivatives of Hexamolybdates

Towards Main-Chain-Polyoxometalate-Containing Hybrid Polymers: A Highly Efficient Approach to Bifunctionalized Organoimido Derivatives of Hexamolybdates

Molybdenum blocks in organic polymers: Bifunctionalized hexamolybdate anions (such as 1) can be selectively synthesized in high yields by using the octamolybdate anion 2 as the starting material. The ion 1 can then be used in the synthesis of the first main‐chain‐polyoxometalate‐containing hybrid po...

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Veröffentlicht in:Angewandte Chemie International Edition 2002-11, Vol.41 (21), p.4129-4132
Hauptverfasser: Xu, Lin, Lu, Meng, Xu, Bubin, Wei, Yongge, Peng, Zhonghua, Powell, Douglas R.
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Sprache:eng
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molybdenum
organic-inorganic hybrid composites
polymers
polyoxometalates
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container_end_page 4132
container_issue 21
container_start_page 4129
container_title Angewandte Chemie International Edition
container_volume 41
creator Xu, Lin
Lu, Meng
Xu, Bubin
Wei, Yongge
Peng, Zhonghua
Powell, Douglas R.
description Molybdenum blocks in organic polymers: Bifunctionalized hexamolybdate anions (such as 1) can be selectively synthesized in high yields by using the octamolybdate anion 2 as the starting material. The ion 1 can then be used in the synthesis of the first main‐chain‐polyoxometalate‐containing hybrid polymer.
doi_str_mv 10.1002/1521-3773(20021104)41:21<4129::AID-ANIE4129>3.0.CO;2-R
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subjects molybdenum
organic-inorganic hybrid composites
polymers
polyoxometalates
title Towards Main-Chain-Polyoxometalate-Containing Hybrid Polymers: A Highly Efficient Approach to Bifunctionalized Organoimido Derivatives of Hexamolybdates
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