Towards Main-Chain-Polyoxometalate-Containing Hybrid Polymers: A Highly Efficient Approach to Bifunctionalized Organoimido Derivatives of Hexamolybdates

Towards Main-Chain-Polyoxometalate-Containing Hybrid Polymers: A Highly Efficient Approach to Bifunctionalized Organoimido Derivatives of Hexamolybdates

Molybdenum blocks in organic polymers: Bifunctionalized hexamolybdate anions (such as 1) can be selectively synthesized in high yields by using the octamolybdate anion 2 as the starting material. The ion 1 can then be used in the synthesis of the first main‐chain‐polyoxometalate‐containing hybrid po...

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Veröffentlicht in:Angewandte Chemie International Edition 2002-11, Vol.41 (21), p.4129-4132
Hauptverfasser: Xu, Lin, Lu, Meng, Xu, Bubin, Wei, Yongge, Peng, Zhonghua, Powell, Douglas R.
Format: Artikel
Sprache:eng
Schlagworte:
molybdenum
organic-inorganic hybrid composites
polymers
polyoxometalates
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Zusammenfassung:Molybdenum blocks in organic polymers: Bifunctionalized hexamolybdate anions (such as 1) can be selectively synthesized in high yields by using the octamolybdate anion 2 as the starting material. The ion 1 can then be used in the synthesis of the first main‐chain‐polyoxometalate‐containing hybrid polymer.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20021104)41:21<4129::AID-ANIE4129>3.0.CO;2-R