Ruthenium-Catalyzed S-Propargylation of Thiols Enables the Rapid Synthesis of Propargylic Sulfides
A new and highly efficient catalytic system based on CpRuClL2 is proposed for the S-propargylation of thiols by propargylic carbonates under neutral conditions, in which specific requirements inherent to the different reactivities of aliphatic and aromatic thiols are achieved by tuning both the natu...
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| Veröffentlicht in: | Journal of the American Chemical Society 2002-11, Vol.124 (44), p.12960-12961 |
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| container_end_page | 12961 |
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| container_issue | 44 |
| container_start_page | 12960 |
| container_title | Journal of the American Chemical Society |
| container_volume | 124 |
| creator | Kondo, Teruyuki Kanda, Yusuke Baba, Atsushi Fukuda, Kenji Nakamura, Ayako Wada, Kenji Morisaki, Yasuhiro Mitsudo, Take-aki |
| description | A new and highly efficient catalytic system based on CpRuClL2 is proposed for the S-propargylation of thiols by propargylic carbonates under neutral conditions, in which specific requirements inherent to the different reactivities of aliphatic and aromatic thiols are achieved by tuning both the nature of the ancillary ligand L and the experimental conditions. |
| doi_str_mv | 10.1021/ja027750o |
| format | Article |
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Am. Chem. Soc</addtitle><date>2002-11-06</date><risdate>2002</risdate><volume>124</volume><issue>44</issue><spage>12960</spage><epage>12961</epage><pages>12960-12961</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>A new and highly efficient catalytic system based on CpRuClL2 is proposed for the S-propargylation of thiols by propargylic carbonates under neutral conditions, in which specific requirements inherent to the different reactivities of aliphatic and aromatic thiols are achieved by tuning both the nature of the ancillary ligand L and the experimental conditions.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>12405818</pmid><doi>10.1021/ja027750o</doi><tpages>2</tpages></addata></record> |
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| ispartof | Journal of the American Chemical Society, 2002-11, Vol.124 (44), p.12960-12961 |
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| language | eng |
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| source | ACS Publications; MEDLINE |
| subjects | Alkynes - chemical synthesis Carbamates - chemistry Catalysis Chemistry Exact sciences and technology Organic chemistry Organometallic Compounds - chemistry Ruthenium - chemistry Sulfhydryl Compounds - chemistry Sulfides - chemical synthesis |
| title | Ruthenium-Catalyzed S-Propargylation of Thiols Enables the Rapid Synthesis of Propargylic Sulfides |
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