Spontaneous assembly of a hydrogen-bonded tetrahedron

Spontaneous assembly of a hydrogen-bonded tetrahedron

Triphenylamine ortho-tricarboxylic acid (1) has been synthesized and the crystal structure reported. This molecule is shown to spontaneously self-assemble into a hydrogen-bonded tetrahedron. Furthermore, Electrospray Ionization Mass Spectroscopy shows evidence for the stability of such aggregates fr...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-10 (19), p.2260-2261
Hauptverfasser: Field, Jason E, Combariza, Marianny Y, Vachet, Richard W, Venkataraman, D
Format: Artikel
Sprache:eng
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Zusammenfassung:Triphenylamine ortho-tricarboxylic acid (1) has been synthesized and the crystal structure reported. This molecule is shown to spontaneously self-assemble into a hydrogen-bonded tetrahedron. Furthermore, Electrospray Ionization Mass Spectroscopy shows evidence for the stability of such aggregates from an ethanol/water solution.
ISSN:1359-7345
1364-548X
DOI:10.1039/b207026j