The Localized-to-Delocalized Transition in Mixed-Valence Chemistry

The Localized-to-Delocalized Transition in Mixed-Valence Chemistry

Demadis et al analyze and categorize the transition between localization and delocalization in ligand-bridged, mixed-valence molecules. The focus is on transition-metal complexes. These molecules reveal the extraordinarily subtle nuances that can be displayed by real mixed-valence molecules in the l...

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Veröffentlicht in:Chemical reviews 2001-09, Vol.101 (9), p.2655-2686
Hauptverfasser: Demadis, Konstantinos D, Hartshorn, Chris M, Meyer, Thomas J
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Metals
Molecules
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Zusammenfassung:Demadis et al analyze and categorize the transition between localization and delocalization in ligand-bridged, mixed-valence molecules. The focus is on transition-metal complexes. These molecules reveal the extraordinarily subtle nuances that can be displayed by real mixed-valence molecules in the localized-to-delocalized transition.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr990413m