Optically active molecule-based magnets: Enantioselective self-assembling, optical, and magnetic properties

Optically active molecule-based magnets: Enantioselective self-assembling, optical, and magnetic properties

In this short communication we describe the synthesis and the optical and magnetic properties of optically active three dimensional (3D) bimetallic [Cr‐Mn] networks {[ΔCrIIIΔMnII(ox)3][ΔRuII(bpy)3]ClO4}n1 − Δ, {[ΛCrIIIΛMnII(ox)3][ΛRuII (bpy)3]ClO4}n 1 − Λ and {[ΔCrIIIΔMnII(ox)3][ΔRuII(bpy)2p p y]}n...

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Veröffentlicht in:Chirality (New York, N.Y.) N.Y.), 2001, Vol.13 (10), p.712-714
Hauptverfasser: Gruselle, Michel, Andres, Roman, Malezieux, Bernard, Brissard, Muriel, Train, Cyrille, Verdaguer, Michel
Format: Artikel
Sprache:eng
Schlagworte:
chirality
chromium
Cotton effect
magnetism
manganese
oxalate
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Zusammenfassung:In this short communication we describe the synthesis and the optical and magnetic properties of optically active three dimensional (3D) bimetallic [Cr‐Mn] networks {[ΔCrIIIΔMnII(ox)3][ΔRuII(bpy)3]ClO4}n1 − Δ, {[ΛCrIIIΛMnII(ox)3][ΛRuII (bpy)3]ClO4}n 1 − Λ and {[ΔCrIIIΔMnII(ox)3][ΔRuII(bpy)2p p y]}n 2 − Δ,{[ΛCrIIIΛMnII(ox)3][ΛRuII(bpy)2ppy]}n 2 − Λ (ox = oxalate, bpy = bipyridine, ppy = phenyl‐pyridine). Chirality 13:712–714, 2001. © 2001 Wiley‐Liss, Inc.
ISSN:0899-0042
1520-636X
DOI:10.1002/chir.10023