Nanostructures via Noncovalent Synthesis:  144 Hydrogen Bonds Bring Together 27 Components

Nanostructures via Noncovalent Synthesis:  144 Hydrogen Bonds Bring Together 27 Components

This paper describes the spontaneous and reversible assembly of ∼20 kDa synthetic hydrogen-bonded assemblies via the formation of 144 cooperative hydrogen bonds. These nanostructures (∼3.0 × 5.5 nm), consisting of 27 different components, have been carefully characterized using a combination of 1H N...

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Veröffentlicht in:Journal of organic chemistry 2001-12, Vol.66 (25), p.8297-8301
Hauptverfasser: Paraschiv, Vasile, Crego-Calama, Mercedes, Fokkens, Roel H, Padberg, Clemens J, Timmerman, P, Reinhoudt, David N
Format: Artikel
Sprache:eng
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Zusammenfassung:This paper describes the spontaneous and reversible assembly of ∼20 kDa synthetic hydrogen-bonded assemblies via the formation of 144 cooperative hydrogen bonds. These nanostructures (∼3.0 × 5.5 nm), consisting of 27 different components, have been carefully characterized using a combination of 1H NMR spectroscopy, MALDI-TOF MS using Ag+-labeling, gel permeation chromatography, and CD spectroscopy.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo0105742