Efficient Strategy for the Synthesis of Stereopentad Subunits of Scytophycin, Rifamycin S, and Discodermolide

Efficient Strategy for the Synthesis of Stereopentad Subunits of Scytophycin, Rifamycin S, and Discodermolide

An efficient, simple method has been developed for the stereocontrolled synthesis of polypropionate stereopentads in high enantio- and diastereomeric purities.

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Veröffentlicht in:Organic letters 2001-12, Vol.3 (25), p.3995-3998
Hauptverfasser: BouzBouz, S, Cossy, J
Format: Artikel
Sprache:eng
Schlagworte:
Aldehydes - chemistry
Alkanes
Antineoplastic Agents - chemical synthesis
Antineoplastic Agents - chemistry
Carbamates
Lactones - chemical synthesis
Lactones - chemistry
Molecular Conformation
Molecular Structure
Pyrans - chemical synthesis
Pyrans - chemistry
Pyrones
Rifamycins - chemical synthesis
Rifamycins - chemistry
Stereoisomerism
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Beschreibung
Zusammenfassung:An efficient, simple method has been developed for the stereocontrolled synthesis of polypropionate stereopentads in high enantio- and diastereomeric purities.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol016250h