Diastereoselective Ruthenium−Cp Complexation of Enantiopure Arene Compounds Possessing Stereogenic Benzylic Alcohol Functionalities

Diastereoselective Ruthenium−Cp Complexation of Enantiopure Arene Compounds Possessing Stereogenic Benzylic Alcohol Functionalities

Enantiopure (arene)ruthenium compounds possessing a stereogenic benzylic alcohol functionality were stereoselectively synthesized by diastereoselective ruthenium−Cp complexation to a distinct arene face. This diastereoselective ruthenium−Cp complexation was further extended to biaryl compounds linke...

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Veröffentlicht in:Organic letters 2001-11, Vol.3 (23), p.3667-3670
Hauptverfasser: Kamikawa, Ken, Furusyo, Masaru, Uno, Takahiro, Sato, Yasuko, Konoo, Atutoshi, Bringmann, Gerhard, Uemura, Motokazu
Format: Artikel
Sprache:eng
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Zusammenfassung:Enantiopure (arene)ruthenium compounds possessing a stereogenic benzylic alcohol functionality were stereoselectively synthesized by diastereoselective ruthenium−Cp complexation to a distinct arene face. This diastereoselective ruthenium−Cp complexation was further extended to biaryl compounds linked with a six-membered lactone bridge for the synthesis of enantiomerically pure, axially chiral biaryls.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol010197f