Avalanche behavior in the dynamics of chemical reactions

Sudden bursts of chemical activity, displaying avalanche-like behavior, have been observed in reactions between metals and liquid electrolytes by measuring the time-dependent chemomagnetic fields with a high-T(c) SQUID. The observed intermittent chemomagnetic field pulses exhibit power-law behavior...

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Veröffentlicht in:Physical review letters 2001-10, Vol.87 (17), p.178303-178303, Article 178303
Hauptverfasser: Claycomb, J R, Bassler, K E, Miller, Jr, J H, Nersesyan, M, Luss, D
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Sprache:eng
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Zusammenfassung:Sudden bursts of chemical activity, displaying avalanche-like behavior, have been observed in reactions between metals and liquid electrolytes by measuring the time-dependent chemomagnetic fields with a high-T(c) SQUID. The observed intermittent chemomagnetic field pulses exhibit power-law behavior in the distributions of peak sizes, noise spectra, and return-time distributions. Such power-law behavior provides evidence for self-organized criticality occurring in the form of "chemical avalanches" over a wide range of size and time scales.
ISSN:0031-9007
1079-7114
DOI:10.1103/PhysRevLett.87.178303