Stereoselective Syntheses of (+)-Goniodiol, (−)-8-Epigoniodiol, and (+)-9-Deoxygoniopypyrone via Alkoxyallylboration and Ring-Closing Metathesis

Stereoselective Syntheses of (+)-Goniodiol, (−)-8-Epigoniodiol, and (+)-9-Deoxygoniopypyrone via Alkoxyallylboration and Ring-Closing Metathesis

A convenient synthesis of (+)-goniodiol, (−)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone has been developed via asymmetric alkoxyallylboration and ring-closing metathesis pathways.

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Veröffentlicht in:Journal of organic chemistry 2002-10, Vol.67 (21), p.7547-7550
Hauptverfasser: Ramachandran, P. Veeraraghavan, Chandra, J. Subash, Ram Reddy, M. Venkat
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Indicators and Reagents
Molecular Conformation
Organic chemistry
Preparations and properties
Pyrones - chemical synthesis
Pyrones - chemistry
Stereoisomerism
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Zusammenfassung:A convenient synthesis of (+)-goniodiol, (−)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone has been developed via asymmetric alkoxyallylboration and ring-closing metathesis pathways.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo0259358