Kinetically induced intermolecular association: unusual enthalpy changes in the nematic phase of a novel dimeric liquid-crystalline molecule

Kinetically induced intermolecular association: unusual enthalpy changes in the nematic phase of a novel dimeric liquid-crystalline molecule

A novel dimeric liquid-crystalline molecule in which two mesogenic groups are connected via catechol was found to have smectic-like layer ordering in the nematic phase, and unusual enthalpy changes were observed in the nematic phase on heating from the monotropic smectic C phase.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-09 (18), p.2060-2061
Hauptverfasser: Yoshizawa, Atsushi, Yamaguchi, Akihisa
Format: Artikel
Sprache:eng
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Zusammenfassung:A novel dimeric liquid-crystalline molecule in which two mesogenic groups are connected via catechol was found to have smectic-like layer ordering in the nematic phase, and unusual enthalpy changes were observed in the nematic phase on heating from the monotropic smectic C phase.
ISSN:1359-7345
DOI:10.1039/b204901p