Unexpected formation of new fluoroboranes from the reaction of NMe4B3H8 with BF3 and MeC identical with CH: exo-2-FB4H9 and trans-MeCH=CHBF2

Unexpected formation of new fluoroboranes from the reaction of NMe4B3H8 with BF3 and MeC identical with CH: exo-2-FB4H9 and trans-MeCH=CHBF2

The new fluoroboranes exo-2-FB4H9 1 and trans-MeCH=CHBF2 2 have been obtained unexpectedly and in good yield from the reaction of tetramethylammonium octahydrotriborate (NMe4B3H8) with boron trifluoride and propyne (MeC identical to CH).

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-09 (18), p.2052-2053
Hauptverfasser: Fox, Mark A, Greatrex, Robert, Ormsby, Daniel L
Format: Artikel
Sprache:eng
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Zusammenfassung:The new fluoroboranes exo-2-FB4H9 1 and trans-MeCH=CHBF2 2 have been obtained unexpectedly and in good yield from the reaction of tetramethylammonium octahydrotriborate (NMe4B3H8) with boron trifluoride and propyne (MeC identical to CH).
ISSN:1359-7345