Coordination polymers of gold(I) with dithiolate and diphosphine ligands

Coordination polymers of gold(I) with dithiolate and diphosphine ligands

The first neutral, hybrid organic-inorganic coordination polymers with linear gold(I) centres in the backbone have the formula [X(OCH2CH2O2CCH2SAu)2(mu-dppee)]n, X = 1,4-C6H4 or C10H6, dppee = trans-bis(diphenylphospino)ethylene, are easily formed by self-assembly during crystallization from macrocy...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-09 (17), p.1834-1835
Hauptverfasser: Hunks, William J, Jennings, Michael C, Puddephatt, Richard J
Format: Artikel
Sprache:eng
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Zusammenfassung:The first neutral, hybrid organic-inorganic coordination polymers with linear gold(I) centres in the backbone have the formula [X(OCH2CH2O2CCH2SAu)2(mu-dppee)]n, X = 1,4-C6H4 or C10H6, dppee = trans-bis(diphenylphospino)ethylene, are easily formed by self-assembly during crystallization from macrocyclic isomers (n = 1), and form sheet structures anchored by secondary Au...S and S...S interactions in the solid state.
ISSN:1359-7345
1364-548X
DOI:10.1039/b204992a