Perfluoroalkylation of simple inorganic molecules: a one step route to novel perfluoroalkylated compounds

Perfluoroalkylation of simple inorganic molecules: a one step route to novel perfluoroalkylated compounds

Reactions of (CH3)3SiRf (Rf = CF3, C2F5) with NOCl, NO/NO2, SO2, CO2, in the presence of caesium fluoride provide a one step synthetic route to perfluoroalkylated compounds in very good yields.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-09 (17), p.1818-1819
Hauptverfasser: Singh, Rajendra P, Shreeve, Jean'ne M
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Reactions of (CH3)3SiRf (Rf = CF3, C2F5) with NOCl, NO/NO2, SO2, CO2, in the presence of caesium fluoride provide a one step synthetic route to perfluoroalkylated compounds in very good yields.
ISSN:1359-7345
1364-548X
DOI:10.1039/b205288c