A Polyhedral Host Constructed Using a Linear Template
A linear template is used to direct the synthesis of a “head-to-head” tetrapyridine in the solid state, which, in a second step, assembles with a transition-metal-ion to form a polyhedral metal-organic host with a structure that conforms to a trigonal antiprism. The application of the linear templat...
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| Veröffentlicht in: | Journal of the American Chemical Society 2002-10, Vol.124 (39), p.11606-11607 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A linear template is used to direct the synthesis of a “head-to-head” tetrapyridine in the solid state, which, in a second step, assembles with a transition-metal-ion to form a polyhedral metal-organic host with a structure that conforms to a trigonal antiprism. The application of the linear template is reminiscent of the synthetic strategy of nature. |
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| ISSN: | 0002-7863 1520-5126 |
| DOI: | 10.1021/ja0278281 |