Axially Bridged Indium Phthalocyanine Dimer with an In----In Bond

Enhanced nonlinear optical response is observed in a soluble dimeric indium–phthalocyanine (Pc) complex stabilized as a Lewis base adduct. The Pc moieties are tilted 14.5° from an axis connecting the In centers, which are out of plane with respect to the Pc macrocycles (see diagram). The InIn separ...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2002-09, Vol.41 (17), p.3239-3242
Hauptverfasser:	Chen, Yu, Barthel, Markus, Seiler, Michael, Subramanian, L.R, Bertagnolli, Helmut, Hanack, Michael
Format:	Artikel
Sprache:	eng
Schlagworte:	dimerization EXAFS spectroscopy indium nonlinear optics phthalocyanines
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Enhanced nonlinear optical response is observed in a soluble dimeric indium–phthalocyanine (Pc) complex stabilized as a Lewis base adduct. The Pc moieties are tilted 14.5° from an axis connecting the In centers, which are out of plane with respect to the Pc macrocycles (see diagram). The InIn separation was calculated to be 3.24 Å by using extended X‐ray absorption fine structure (EXAFS) spectroscopy.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/1521-3773(20020902)41:17<3239::AID-ANIE3239>3.0.CO;2-F