Isolation of a new mixed valence Pt molecular oxide using phosphine as protecting group

Isolation of a new mixed valence Pt molecular oxide using phosphine as protecting group

A novel tetranuclear mixed valence cationic Pt molecular oxide [((Me3P)2Pt)3Pt(OH)6]4+ is obtained by reacting H2Pt(OH)6 and (Me3P)2Pt2+, whose NMR spectra suggest the existence of another species in solution that may serve as a starting point for further synthesis of Pt molecular oxides.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-08 (16), p.1770-1771
Hauptverfasser: Noro, K, Ozawa, Y, Taguchi, M, Yagasaki, A
Format: Artikel
Sprache:eng
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Zusammenfassung:A novel tetranuclear mixed valence cationic Pt molecular oxide [((Me3P)2Pt)3Pt(OH)6]4+ is obtained by reacting H2Pt(OH)6 and (Me3P)2Pt2+, whose NMR spectra suggest the existence of another species in solution that may serve as a starting point for further synthesis of Pt molecular oxides.
ISSN:1359-7345
1364-548X
DOI:10.1039/b204804c