Synthesis and characterization of the hexagonal prismatic cage [THF[subset or is implied by][PhB(CN)(3)](6)[CpRh](6)](6+)

Synthesis and characterization of the hexagonal prismatic cage [THF[subset or is implied by][PhB(CN)(3)](6)[CpRh](6)](6+)

Condensation of [Cp*Rh(CH(3)NO(2))(n)](2+) and the tricyanoborate [PhB(CN)(3)](-) affords the hexagonal bipyramidal cage [[PhB(CN)(3)](6)[Cp*Rh](6)](6+), demonstrating that tetrahedral tricyanide building blocks can lead to novel cage structures.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-06 (12), p.1370-1371
Hauptverfasser: Kuhlman, Matthew L, Yao, Haijun, Rauchfuss, Thomas B
Format: Artikel
Sprache:eng
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Zusammenfassung:Condensation of [Cp*Rh(CH(3)NO(2))(n)](2+) and the tricyanoborate [PhB(CN)(3)](-) affords the hexagonal bipyramidal cage [[PhB(CN)(3)](6)[Cp*Rh](6)](6+), demonstrating that tetrahedral tricyanide building blocks can lead to novel cage structures.
ISSN:1359-7345
DOI:10.1039/b401505c