Benzyl anion abstraction from a (beta-diiminato)Fe(II) benzyl complex

Benzyl anion abstraction from a (beta-diiminato)Fe(II) benzyl complex

The 3-coordinate 12 VE iron(II) benzyl complex [(nacnac)-Fe(CH2Ph)] reacts with B(C6F5)3 to yield a paramagnetic contact ion pair with an eta 2-(o,m)-[PhCH2B(C6F5)3] anion, which was characterised by X-ray diffraction.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-08 (15), p.1580-1581
Hauptverfasser: Sciarone, Timo J J, Meetsma, Auke, Hesssen, Bart, Teuben, Jan H
Format: Artikel
Sprache:eng
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Zusammenfassung:The 3-coordinate 12 VE iron(II) benzyl complex [(nacnac)-Fe(CH2Ph)] reacts with B(C6F5)3 to yield a paramagnetic contact ion pair with an eta 2-(o,m)-[PhCH2B(C6F5)3] anion, which was characterised by X-ray diffraction.
ISSN:1359-7345
DOI:10.1039/b204454d