A novel isopolytungstate functionalized by ruthenium: [HW(9)O(33)Ru(II)(2)(dmso)(6)](7-)

A novel isopolytungstate functionalized by ruthenium: [HW(9)O(33)Ru(II)(2)(dmso)(6)](7-)

The ruthenium-supported isopolyanion [HW(9)O(33)Ru(II)(2)(dmso)(6)](7-) (1) is composed of a nonatungstate wheel stabilized by two Ru(dmso)(3) groups, representing the first structurally characterized Ru-coordinated polyoxotungstate and a novel class of isopolyanions supporting photochromic moieties...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-06 (12), p.1420-1421
Hauptverfasser: Bi, Lihua, Hussain, Firasat, Kortz, Ulrich, Sadakane, Masahiro, Dickman, Michael H
Format: Artikel
Sprache:eng
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Zusammenfassung:The ruthenium-supported isopolyanion [HW(9)O(33)Ru(II)(2)(dmso)(6)](7-) (1) is composed of a nonatungstate wheel stabilized by two Ru(dmso)(3) groups, representing the first structurally characterized Ru-coordinated polyoxotungstate and a novel class of isopolyanions supporting photochromic moieties.
ISSN:1359-7345
DOI:10.1039/b403902e