Supramolecular Stereocontrol of Octahedral Metal-Centered Chirality. Ligand Modulation
By associating chiral labile [FeL3]2+ complexes with TRISPHAT anions, a stereocontrol of the metal-centered chirality is feasible; the sense of the stereoselective induction and its magnitude strongly depends upon the structure of the diimine ligands (L: bpy, phen).
Gespeichert in:
| Veröffentlicht in: | Inorganic chemistry 2004-05, Vol.43 (11), p.3329-3331 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | By associating chiral labile [FeL3]2+ complexes with TRISPHAT anions, a stereocontrol of the metal-centered chirality is feasible; the sense of the stereoselective induction and its magnitude strongly depends upon the structure of the diimine ligands (L: bpy, phen). |
|---|---|
| ISSN: | 0020-1669 1520-510X |
| DOI: | 10.1021/ic049661d |