Molecular Triangle of Palladium(II) and Its Anion Binding Properties

Molecular Triangle of Palladium(II) and Its Anion Binding Properties

The ligand 4(3H)-pyrimidone (Hpm) forms the complexes trans-[PdCl2(Hpm)2] and [Pd(PP)(Hpm)2](CF3SO3)2 (PP = Ph2PCH2PPh2 or Ph2P(CH2)3PPh2), with the neutral ligand (Hpm), and a bowl-like molecular triangle, [{Pd(bu2bipy)(μ-pm)}3]3+ (bu2bipy = 4,4‘-di-tert-butyl-2,2‘-bipyridine), with the deprotonate...

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Veröffentlicht in:Inorganic chemistry 2002-07, Vol.41 (15), p.3967-3974
Hauptverfasser: Qin, Zengquan, Jennings, Michael C, Puddephatt, Richard J
Format: Artikel
Sprache:eng
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Zusammenfassung:The ligand 4(3H)-pyrimidone (Hpm) forms the complexes trans-[PdCl2(Hpm)2] and [Pd(PP)(Hpm)2](CF3SO3)2 (PP = Ph2PCH2PPh2 or Ph2P(CH2)3PPh2), with the neutral ligand (Hpm), and a bowl-like molecular triangle, [{Pd(bu2bipy)(μ-pm)}3]3+ (bu2bipy = 4,4‘-di-tert-butyl-2,2‘-bipyridine), with the deprotonated ligand (pm). This triangular complex acts as a host for binding of several anionic guests.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic020227q