The rational design of novel chiral oxovanadium(IV) complexes for highly enantioselective oxidative coupling of 2-naphthols

The rational design of novel chiral oxovanadium(IV) complexes for highly enantioselective oxidative coupling of 2-naphthols

Several novel chiral oxovanadium(IV) complexes have been designed and prepared for the asymmetric catalytic oxidative coupling of 2-naphthols with high enantioselectivities of 83-98% ee.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-04 (8), p.914-915
Hauptverfasser: Luo, Zhibin, Liu, Quanzhong, Gong, Liuzhu, Cui, Xin, Mi, Aiqiao, Jiang, Yaozhong
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemistry, Organic
Hydrogen-Ion Concentration
Molecular Structure
Naphthols - chemical synthesis
Naphthols - chemistry
Naphthols - metabolism
Organic Chemistry Phenomena
Oxidation-Reduction
Stereoisomerism
Vanadates - chemical synthesis
Vanadates - chemistry
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Beschreibung
Zusammenfassung:Several novel chiral oxovanadium(IV) complexes have been designed and prepared for the asymmetric catalytic oxidative coupling of 2-naphthols with high enantioselectivities of 83-98% ee.
ISSN:1359-7345
DOI:10.1039/b201351g