Synthesis and crystal structure of a novel decanuclear silver cluster complex [Ag(SC6H2Pri(3)-2,4,6)](10).2CHCI3.C2H5OH
The cluster [Ag(SC6H2Pri(3)-2,4,6)]10 (1) contains a 20-membered ring of alternating silver and sulfur atoms, which is compactly folded; the sulfur atoms are doubly bridging and each silver atom exhibits linear two-coordination in the primary Ag-S interactions.
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2002-03 (6), p.600-601 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The cluster [Ag(SC6H2Pri(3)-2,4,6)]10 (1) contains a 20-membered ring of alternating silver and sulfur atoms, which is compactly folded; the sulfur atoms are doubly bridging and each silver atom exhibits linear two-coordination in the primary Ag-S interactions. |
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ISSN: | 1359-7345 |