Synthesis and crystal structure of a novel decanuclear silver cluster complex [Ag(SC6H2Pri(3)-2,4,6)](10).2CHCI3.C2H5OH

The cluster [Ag(SC6H2Pri(3)-2,4,6)]10 (1) contains a 20-membered ring of alternating silver and sulfur atoms, which is compactly folded; the sulfur atoms are doubly bridging and each silver atom exhibits linear two-coordination in the primary Ag-S interactions.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-03 (6), p.600-601
Hauptverfasser: Jin, Xianglin, Xie, Xiangjin, Qian, Hua, Tang, Kaluo, Liu, Chunling, Wang, Xin, Gong, Qihuang
Format: Artikel
Sprache:eng
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Zusammenfassung:The cluster [Ag(SC6H2Pri(3)-2,4,6)]10 (1) contains a 20-membered ring of alternating silver and sulfur atoms, which is compactly folded; the sulfur atoms are doubly bridging and each silver atom exhibits linear two-coordination in the primary Ag-S interactions.
ISSN:1359-7345