Deracemisation and stereoinversion of alpha-amino acids using D-amino acid oxidase and hydride reducing agents

Deracemisation and stereoinversion of alpha-amino acids using D-amino acid oxidase and hydride reducing agents

The deracemisation and stereoinversion of both cyclic and acyclic DL-alpha-amino acids, using porcine kidney D-amino acid oxidase (DAAO) and a hydride reducing agent (NaCNBH3-NaBH4), has been investigated.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-02 (3), p.246-247
Hauptverfasser: Beard, Timothy M, Turner, Nicholas J
Format: Artikel
Sprache:eng
Schlagworte:
Amino Acids - chemistry
D-Amino-Acid Oxidase - chemistry
Hydrogen - chemistry
Reducing Agents - chemistry
Stereoisomerism
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Zusammenfassung:The deracemisation and stereoinversion of both cyclic and acyclic DL-alpha-amino acids, using porcine kidney D-amino acid oxidase (DAAO) and a hydride reducing agent (NaCNBH3-NaBH4), has been investigated.
ISSN:1359-7345
1364-548X
DOI:10.1039/b107580m