Planar and central chiral [2.2]paracyclophane-based N,O-ligands as highly active catalysts in the diethylzinc addition to aldehydes

Planar and central chiral [2.2]paracyclophane-based N,O-ligands as highly active catalysts in the diethylzinc addition to aldehydes

The application of planar and central chiral [2.2]paracyclophane-based N,O-ligands in asymmetric diethylzinc additions to various aldehydes is described revealing an unusual substrate spectrum for the catalysts and their remarkably high activity.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-01 (1), p.26-27
Hauptverfasser: Dahmen, Stefan, Bräse, Stefan
Format: Artikel
Sprache:eng
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Zusammenfassung:The application of planar and central chiral [2.2]paracyclophane-based N,O-ligands in asymmetric diethylzinc additions to various aldehydes is described revealing an unusual substrate spectrum for the catalysts and their remarkably high activity.
ISSN:1359-7345
DOI:10.1039/b108347c