Selective oxidation of cyclooctane to cyclootanone with molecular oxygen in the presence of compressed carbon dioxide

Selective oxidation of cyclooctane to cyclootanone with molecular oxygen in the presence of compressed carbon dioxide

The oxidation of cyclooctane (1) to cyclooctanone (3) with molecular oxygen and acetaldehyde (2) as a co-reductant occurs efficiently in the presence of compressed CO2. Up to 20% yields of 3 are obtained under optimised multiphase conditions.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-03 (5), p.410-411
Hauptverfasser: Theyssen, Nils, Leitner, Walter
Format: Artikel
Sprache:eng
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Zusammenfassung:The oxidation of cyclooctane (1) to cyclooctanone (3) with molecular oxygen and acetaldehyde (2) as a co-reductant occurs efficiently in the presence of compressed CO2. Up to 20% yields of 3 are obtained under optimised multiphase conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/b111212k