Coordination Chemistry of Fluorine in Fluorocarbons

Fluorine can do it. Not only oxygen but also fluorine, covalently bonded in organic molecules, is an important donor atom in the coordination chemistry of biorelevant metal ions such as Na+, K+, Mg2+ and Ca2+. Clear evidence in favour of such interactions will be presented in this Minireview, follow...

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Veröffentlicht in:	Chembiochem : a European journal of chemical biology 2004-05, Vol.5 (5), p.650-655
1. Verfasser:	Plenio, Herbert
Format:	Artikel
Sprache:	eng
Schlagworte:	alkali metals alkaline earth metals coordination chemistry Crown Ethers - chemistry Crystallography, X-Ray fluorine Fluorine - chemistry fluorine-containing drugs Fluorocarbons - chemistry Hydrocarbons, Fluorinated - chemistry Ligands Magnetic Resonance Spectroscopy - methods Metals - chemistry Models, Molecular Molecular Structure
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Beschreibung
Zusammenfassung:	Fluorine can do it. Not only oxygen but also fluorine, covalently bonded in organic molecules, is an important donor atom in the coordination chemistry of biorelevant metal ions such as Na+, K+, Mg2+ and Ca2+. Clear evidence in favour of such interactions will be presented in this Minireview, followed by a discussion of possible implications for fluorinated, bioactive compounds.
ISSN:	1439-4227 1439-7633
DOI:	10.1002/cbic.200300752