Highly saddle shaped (porphyrinato)iron(III) iodide with a pure intermediate spin state

Highly saddle shaped (porphyrinato)iron(III) iodide with a pure intermediate spin state

Combined analyses using NMR, EPR and Mössbauer spectroscopy as well as SQUID magnetometry have revealed that highly saddle shaped Fe(OETPP)I adopts an essentially pure intermediate spin state in spite of the coordination of an iodide ligand.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-06 (11), p.1198-1199
Hauptverfasser: Nakamura, Mikio, Ikeue, Takahisa, Ohgo, Yoshiki, Takahashi, Masashi, Takeda, Masuo
Format: Artikel
Sprache:eng
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Zusammenfassung:Combined analyses using NMR, EPR and Mössbauer spectroscopy as well as SQUID magnetometry have revealed that highly saddle shaped Fe(OETPP)I adopts an essentially pure intermediate spin state in spite of the coordination of an iodide ligand.
ISSN:1359-7345
1364-548X
DOI:10.1039/b202768b