A Facile One-Pot Synthesis of Alkyl Aryl Sulfides from Aryl Bromides

A convenient one-pot synthetic method for the formation of alkyl aryl sulfides from various alkyl halides and lithium aryl thiolates that are prepared in situ by direct halogen−lithium exchange is reported. In particular, the method overcomes many of the problems encountered in previous reports; it...

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Veröffentlicht in:	Journal of organic chemistry 2004-04, Vol.69 (9), p.3236-3239
Hauptverfasser:	Ham, Jungyeob, Yang, Inho, Kang, Heonjoong
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Noncondensed benzenic compounds Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A convenient one-pot synthetic method for the formation of alkyl aryl sulfides from various alkyl halides and lithium aryl thiolates that are prepared in situ by direct halogen−lithium exchange is reported. In particular, the method overcomes many of the problems encountered in previous reports; it is very quick, catalyst-free, and does not involve use of unstable aryl thiols.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo049758h