Chemical transformation of lactose into 4- O-β- d-galactopyranosyl- d-glucuronic acid (pseudolactobiouronic acid) and some derivatives thereof

The selective oxidation of the primary alcoholic function of the reducing unit of lactose was achieved in good overall yield (67%) starting from 2′,6′-di- O-benzyl-2,3:3′,4′-di- O-isopropylidenelactose dimethyl acetal ( 1) through a simple multi-step procedure based on the selective acetylation of O...

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Veröffentlicht in:	Carbohydrate research 2002-06, Vol.337 (11), p.991-996
Hauptverfasser:	Attolino, Emanuele, Catelani, Giorgio, D'Andrea, Felicia, Puccioni, Leonardo
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylation Carbohydrate Sequence Glucuronates Glucuronic Acid - chemical synthesis Lactose Lactose - chemistry Molecular Sequence Data Oxidations Pseudoaldobiouronic acids Pseudolactobiouronic acid
Online-Zugang:	Volltext
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