Use of allene in 1,3-dipolar addition to a carbonyl ylide: syntheses of 3-hydroxy-cis-nemorensic acid and nemorensic acid

Use of allene in 1,3-dipolar addition to a carbonyl ylide: syntheses of 3-hydroxy-cis-nemorensic acid and nemorensic acid

1,3-Dipolar addition of allene to the carbonyl ylide derived from 6-diazoheptane-2,5-dione is the key step in syntheses of 3-hydroxy-cis-nemorensic acid and nemorensic acid.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-04 (7), p.822-823
Hauptverfasser: Hodgson, David M, Le Strat, Frédéric
Format: Artikel
Sprache:eng
Schlagworte:
Alkadienes - chemistry
Azo Compounds - chemistry
Furans - chemical synthesis
Heptanes - chemistry
Models, Chemical
Pyrrolizidine Alkaloids - chemical synthesis
Stereoisomerism
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Zusammenfassung:1,3-Dipolar addition of allene to the carbonyl ylide derived from 6-diazoheptane-2,5-dione is the key step in syntheses of 3-hydroxy-cis-nemorensic acid and nemorensic acid.
ISSN:1359-7345
1364-548X
DOI:10.1039/b316908a