Building block syntheses of site-isolated vanadyl groups in silicate oxides

Building block syntheses of site-isolated vanadyl groups in silicate oxides

Cross-linking of the cubic silicate building block, Si8O20 with vanadyl chloride leads to porous solids in which a homogeneous dispersion of isolated vanadyl groups is maintained throughout the matrix even at high loadings of vanadium.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-04 (7), p.856-857
Hauptverfasser: Ghosh, Narendra N, Clark, Jason C, Eldridge, Geoffrey T, Barnes, Craig E
Format: Artikel
Sprache:eng
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Zusammenfassung:Cross-linking of the cubic silicate building block, Si8O20 with vanadyl chloride leads to porous solids in which a homogeneous dispersion of isolated vanadyl groups is maintained throughout the matrix even at high loadings of vanadium.
ISSN:1359-7345
DOI:10.1039/b316184f