Cross-metathesis reactions of vinyl-chlorins and -porphyrins catalyzed by a "second generation" Grubbs' catalyst

Cross-metathesis reactions of vinyl-chlorins and -porphyrins catalyzed by a "second generation" Grubbs' catalyst

The first application of olefin cross-metathesis with vinylchlorins and vinylporphyrins using a "second generation" Grubbs' catalyst is reported. Cross-metathesis products were obtained in good yields with high E-stereoselectivity.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-04 (7), p.852-853
Hauptverfasser: Liu, Xin, Sternberg, Ethan, Dolphin, David
Format: Artikel
Sprache:eng
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Zusammenfassung:The first application of olefin cross-metathesis with vinylchlorins and vinylporphyrins using a "second generation" Grubbs' catalyst is reported. Cross-metathesis products were obtained in good yields with high E-stereoselectivity.
ISSN:1359-7345
1364-548X
DOI:10.1039/b400001c