Enyne Metathesis (Enyne Bond Reorganization)

Enyne Metathesis (Enyne Bond Reorganization)

Enzyne metathesis is a bond reorganization of an alkene and an alkyne to produce a 1,3-diene. For the metal carbene-catalyzed enzyne metathesis, there are mechanistic parallels with alkene metathesis. Diver and Giessert address these similarities where relevant and where they are reasonably well-stu...

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Veröffentlicht in:Chemical reviews 2004-03, Vol.104 (3), p.1317-1382
Hauptverfasser: Diver, Steven T, Giessert, Anthony J
Format: Artikel
Sprache:eng
Schlagworte:
Alkalies
Alkynes - chemistry
Amino Acids - chemistry
Biological Factors - chemistry
Carbohydrates - chemistry
Chemical bonds
Chemical synthesis
Chemistry
Heterocyclic Compounds - chemical synthesis
Heterocyclic Compounds - chemistry
Hydrocarbons
Isomerism
Metals - chemistry
Methane - analogs & derivatives
Methane - chemistry
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Beschreibung
Zusammenfassung:Enzyne metathesis is a bond reorganization of an alkene and an alkyne to produce a 1,3-diene. For the metal carbene-catalyzed enzyne metathesis, there are mechanistic parallels with alkene metathesis. Diver and Giessert address these similarities where relevant and where they are reasonably well-studied.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr020009e