Revelations in Dinitrogen Activation and Functionalization by Metal Complexes

A monumental achievement for coordination chemistry that also re‐addresses the role of molybdenum in the nitrogenase FeMo cofactor is the discovery of the catalytic reduction of dinitrogen at a well‐defined molybdenum complex by protons and electrons (see picture).

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Veröffentlicht in:	Angewandte Chemie International Edition 2004-02, Vol.43 (10), p.1186-1189
Hauptverfasser:	Kozak, Christopher M., Mountford, Philip
Format:	Artikel
Sprache:	eng
Schlagworte:	Ammonia - chemical synthesis coordination modes enzyme catalysis Iron - chemistry Ligands molybdenum Molybdenum - chemistry Molybdoferredoxin - chemistry Nitrogen - chemistry Nitrogen - metabolism Nitrogen Fixation Nitrogenase - chemistry Nitrogenase - metabolism nitrogenases Oxidation-Reduction Tantalum - chemistry
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Beschreibung
Zusammenfassung:	A monumental achievement for coordination chemistry that also re‐addresses the role of molybdenum in the nitrogenase FeMo cofactor is the discovery of the catalytic reduction of dinitrogen at a well‐defined molybdenum complex by protons and electrons (see picture).
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200301712