Orthogonally Functionalized Oligomers for Controlled Self-Assembly
The synthesis of molecules terminated with complementary thiol-protecting groups is described. The target compounds contain functionalities on one end known to form self-assembled monolayers on metal surfaces while at the other end an intact thioacetate is present whereby self-assembly may again occ...
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Veröffentlicht in: | Journal of organic chemistry 2004-03, Vol.69 (5), p.1752-1755 |
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container_title | Journal of organic chemistry |
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creator | Flatt, Austen K Yao, Yuxing Maya, Francisco Tour, James M |
description | The synthesis of molecules terminated with complementary thiol-protecting groups is described. The target compounds contain functionalities on one end known to form self-assembled monolayers on metal surfaces while at the other end an intact thioacetate is present whereby self-assembly may again occur after an in situ deprotection. Self-assembly data is reported for selected compounds to assess their efficacy in surface adhesion. |
doi_str_mv | 10.1021/jo035821b |
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The target compounds contain functionalities on one end known to form self-assembled monolayers on metal surfaces while at the other end an intact thioacetate is present whereby self-assembly may again occur after an in situ deprotection. 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Org. Chem</addtitle><description>The synthesis of molecules terminated with complementary thiol-protecting groups is described. The target compounds contain functionalities on one end known to form self-assembled monolayers on metal surfaces while at the other end an intact thioacetate is present whereby self-assembly may again occur after an in situ deprotection. Self-assembly data is reported for selected compounds to assess their efficacy in surface adhesion.</description><subject>Applied sciences</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Noncondensed benzenic compounds</subject><subject>Organic chemistry</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Preparations and properties</subject><subject>Properties and characterization</subject><subject>Solid-liquid interface</subject><subject>Surface physical chemistry</subject><subject>Surface properties</subject><issn>0022-3263</issn><issn>1520-6904</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqF0U9r2zAYBnBRVtYs26FfoOSywQ5eX_21dMySdhsEUohPuwjZkVqnspVKNjT79HWXkFwK1UWI98eD9AihSww_MBB8vQlAuSS4PEMjzAlkQgH7gEYAhGSUCHqBPqW0gWFxzj-iC8yUzIGREfq5jN1DuA-t8X43ue3bqqtfD_U_u54sfX0fGhvTxIU4mYW2i8H7YbCy3mXTlGxT-t1ndO6MT_bLYR-j4vammP3OFstff2bTRWYYqC6TKjfM4FI6poSiYJnI89xK5mzpONA1ZpIDcw4osYxLCooyWcIaYyqsoGP0bR-7jeGpt6nTTZ0q671pbeiTzrGQWGI-wO97WMWQUrROb2PdmLjTGPRrX_rY12CvDqF92dj1SR4KGsDXAzCpMt5F01Z1OjkhqBKYvus4x5L8z8v2rk6dfT7OTXzUIqc518XdShfzv3O1UEQXp1xTpeHefRz-Jr3xkBeZ-5jn</recordid><startdate>20040305</startdate><enddate>20040305</enddate><creator>Flatt, Austen K</creator><creator>Yao, Yuxing</creator><creator>Maya, Francisco</creator><creator>Tour, James M</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20040305</creationdate><title>Orthogonally Functionalized Oligomers for Controlled Self-Assembly</title><author>Flatt, Austen K ; Yao, Yuxing ; Maya, Francisco ; Tour, James M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a409t-897a4a1b8f496930e46777e84febf503d148504ff032e458309348b0d1136e63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Noncondensed benzenic compounds</topic><topic>Organic chemistry</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Preparations and properties</topic><topic>Properties and characterization</topic><topic>Solid-liquid interface</topic><topic>Surface physical chemistry</topic><topic>Surface properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Flatt, Austen K</creatorcontrib><creatorcontrib>Yao, Yuxing</creatorcontrib><creatorcontrib>Maya, Francisco</creatorcontrib><creatorcontrib>Tour, James M</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Flatt, Austen K</au><au>Yao, Yuxing</au><au>Maya, Francisco</au><au>Tour, James M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Orthogonally Functionalized Oligomers for Controlled Self-Assembly</atitle><jtitle>Journal of organic chemistry</jtitle><addtitle>J. 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subjects | Applied sciences Chemistry Exact sciences and technology General and physical chemistry Noncondensed benzenic compounds Organic chemistry Organic polymers Physicochemistry of polymers Preparations and properties Properties and characterization Solid-liquid interface Surface physical chemistry Surface properties |
title | Orthogonally Functionalized Oligomers for Controlled Self-Assembly |
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