Orthogonally Functionalized Oligomers for Controlled Self-Assembly

The synthesis of molecules terminated with complementary thiol-protecting groups is described. The target compounds contain functionalities on one end known to form self-assembled monolayers on metal surfaces while at the other end an intact thioacetate is present whereby self-assembly may again occ...

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Veröffentlicht in:Journal of organic chemistry 2004-03, Vol.69 (5), p.1752-1755
Hauptverfasser: Flatt, Austen K, Yao, Yuxing, Maya, Francisco, Tour, James M
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container_issue 5
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container_title Journal of organic chemistry
container_volume 69
creator Flatt, Austen K
Yao, Yuxing
Maya, Francisco
Tour, James M
description The synthesis of molecules terminated with complementary thiol-protecting groups is described. The target compounds contain functionalities on one end known to form self-assembled monolayers on metal surfaces while at the other end an intact thioacetate is present whereby self-assembly may again occur after an in situ deprotection. Self-assembly data is reported for selected compounds to assess their efficacy in surface adhesion.
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source American Chemical Society Journals
subjects Applied sciences
Chemistry
Exact sciences and technology
General and physical chemistry
Noncondensed benzenic compounds
Organic chemistry
Organic polymers
Physicochemistry of polymers
Preparations and properties
Properties and characterization
Solid-liquid interface
Surface physical chemistry
Surface properties
title Orthogonally Functionalized Oligomers for Controlled Self-Assembly
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