Orthogonally Functionalized Oligomers for Controlled Self-Assembly

The synthesis of molecules terminated with complementary thiol-protecting groups is described. The target compounds contain functionalities on one end known to form self-assembled monolayers on metal surfaces while at the other end an intact thioacetate is present whereby self-assembly may again occ...

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Veröffentlicht in:	Journal of organic chemistry 2004-03, Vol.69 (5), p.1752-1755
Hauptverfasser:	Flatt, Austen K, Yao, Yuxing, Maya, Francisco, Tour, James M
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Chemistry Exact sciences and technology General and physical chemistry Noncondensed benzenic compounds Organic chemistry Organic polymers Physicochemistry of polymers Preparations and properties Properties and characterization Solid-liquid interface Surface physical chemistry Surface properties
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Beschreibung
Zusammenfassung:	The synthesis of molecules terminated with complementary thiol-protecting groups is described. The target compounds contain functionalities on one end known to form self-assembled monolayers on metal surfaces while at the other end an intact thioacetate is present whereby self-assembly may again occur after an in situ deprotection. Self-assembly data is reported for selected compounds to assess their efficacy in surface adhesion.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo035821b