Pi-donor BETS based bifunctional superconductor with polymeric dicyanamidomanganate(II) anion layer: kappa-(BETS)2Mn[N(CN)2]3

Pi-donor BETS based bifunctional superconductor with polymeric dicyanamidomanganate(II) anion layer: kappa-(BETS)2Mn[N(CN)2]3

Crystals of the bis(ethylenedithio)tetraselenafulvalene (BETS) radical cation salt with dicyanamidomanganate(II) anion, kappa-(BETS)2Mn[N(CN)2]3, were synthesized, which combine conducting and magnetic properties at ambient pressure and are superconducting (Tc approximately/= 5 K) at a moderate pres...

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Veröffentlicht in:Journal of the American Chemical Society 2008-06, Vol.130 (23), p.7238-7240
Hauptverfasser: Kushch, Nataliya D, Yagubskii, Eduard B, Kartsovnik, Mark V, Buravov, Lev I, Dubrovskii, Alexander D, Chekhlov, Anatolii N, Biberacher, Werner
Format: Artikel
Sprache:eng
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Zusammenfassung:Crystals of the bis(ethylenedithio)tetraselenafulvalene (BETS) radical cation salt with dicyanamidomanganate(II) anion, kappa-(BETS)2Mn[N(CN)2]3, were synthesized, which combine conducting and magnetic properties at ambient pressure and are superconducting (Tc approximately/= 5 K) at a moderate pressure of 0.3 kbar.
ISSN:1520-5126
DOI:10.1021/ja801841q