Pressure-induced superconductivity in CaLi(2)

A search for superconductivity has been carried out on the hexagonal polymorph of Laves-phase CaLi(2), a compound for which Feng, Ashcroft, and Hoffmann predict highly anomalous behavior under pressure. No superconductivity is observed above 1.10 K at ambient pressure. However, high-pressure ac susc...

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Veröffentlicht in:Physical review letters 2008-05, Vol.100 (19), p.197003-197003
Hauptverfasser: Matsuoka, T, Debessai, M, Hamlin, J J, Gangopadhyay, A K, Schilling, J S, Shimizu, K
Format: Artikel
Sprache:eng
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Zusammenfassung:A search for superconductivity has been carried out on the hexagonal polymorph of Laves-phase CaLi(2), a compound for which Feng, Ashcroft, and Hoffmann predict highly anomalous behavior under pressure. No superconductivity is observed above 1.10 K at ambient pressure. However, high-pressure ac susceptibility and electrical resistivity studies to 81 GPa reveal bulk superconductivity in CaLi(2) at temperatures as high as 13 K. The normal-state resistivity displays a dramatic increase with pressure.
ISSN:0031-9007