Palladium-Catalyzed Tandem Cyclization of Allenyl-Aldehydes and -Ketones with Aryl Iodides and Bu3SnSnBu3

Palladium-Catalyzed Tandem Cyclization of Allenyl-Aldehydes and -Ketones with Aryl Iodides and Bu3SnSnBu3

The arylative cyclization of allenyl-aldehydes with aryl iodides and hexa-n-butyldistannane to form substituted cyclopentanols and cyclohexanols by tandem palladium-catalyzed carbostannylation and allylation was achieved under mild conditions.

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Veröffentlicht in:Organic letters 2002-04, Vol.4 (7), p.1143-1146
Hauptverfasser: Ha, Young-Hwan, Kang, Suk-Ku
Format: Artikel
Sprache:eng
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Zusammenfassung:The arylative cyclization of allenyl-aldehydes with aryl iodides and hexa-n-butyldistannane to form substituted cyclopentanols and cyclohexanols by tandem palladium-catalyzed carbostannylation and allylation was achieved under mild conditions.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol025557t