Crown-ether functionalised second coordination sphere palladium catalysts by molecular imprinting

Crown-ether functionalised second coordination sphere palladium catalysts by molecular imprinting

Functionalisation of the second coordination sphere of a molecularly imprinted Pd complex was achieved by localising within the polymeric cavity a crown-ether receptor capable of altering the catalytic activity of the reactive site.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2003-12 (24), p.3040-3041
Hauptverfasser: Viton, Florian, White, Peter S, Gagné, Michel R
Format: Artikel
Sprache:eng
Schlagworte:
Binding Sites
Biomimetics
Catalysis
Cross-Linking Reagents - chemistry
Crown Ethers - chemistry
Organometallic Compounds - chemistry
Palladium - chemistry
Polymers - chemistry
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Zusammenfassung:Functionalisation of the second coordination sphere of a molecularly imprinted Pd complex was achieved by localising within the polymeric cavity a crown-ether receptor capable of altering the catalytic activity of the reactive site.
ISSN:1359-7345
1364-548X
DOI:10.1039/b309072h