Development of a Highly Efficient Catalytic Method for Synthesis of Vinyl Ethers

A new method for the preparation of alkyl vinyl ethers has been developed. Thus, various types of alkyl vinyl ethers were synthesized by the reaction of alcohols with vinyl acetate under the influence of a catalytic amount of [Ir(cod)Cl]2 combined with Na2CO3 in good to excellent yields.

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Veröffentlicht in:Journal of the American Chemical Society 2002-02, Vol.124 (8), p.1590-1591
Hauptverfasser: Okimoto, Yoshio, Sakaguchi, Satoshi, Ishii, Yasutaka
Format: Artikel
Sprache:eng
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Zusammenfassung:A new method for the preparation of alkyl vinyl ethers has been developed. Thus, various types of alkyl vinyl ethers were synthesized by the reaction of alcohols with vinyl acetate under the influence of a catalytic amount of [Ir(cod)Cl]2 combined with Na2CO3 in good to excellent yields.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja0173932