A mannitol teichoic acid containing rhamnose and pyruvic acid acetal from the cell wall of Brevibacterium permense VKM Ac-2280

The cell wall of Brevibacterium permense VKM Ac-2280 contains two teichoic acids. The major polymer represents a 1,6-poly(mannitol phosphate) substituted wirh either l-rhamnose (∼70%, unit A) or ( S)-acetal of pyruvic acid (∼30%, unit B) with the overall chain length ∼10 mannitol phosphate units. Th...

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Veröffentlicht in:Carbohydrate research 2003-11, Vol.338 (23), p.2745-2749
Hauptverfasser: Potekhina, Natalia V, Shashkov, Alexander S, Evtushenko, Lyudmila I, Senchenkova, Sof'ya N, Naumova, Irina B
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Sprache:eng
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Zusammenfassung:The cell wall of Brevibacterium permense VKM Ac-2280 contains two teichoic acids. The major polymer represents a 1,6-poly(mannitol phosphate) substituted wirh either l-rhamnose (∼70%, unit A) or ( S)-acetal of pyruvic acid (∼30%, unit B) with the overall chain length ∼10 mannitol phosphate units. The other polymer is an unsubstituted 1,3-poly(glycerol phosphate). The structures of the polymers were established using chemical degradations and NMR spectroscopy. The data obtained may be helpful in determination of the species-specific status of newly isolated Brevibacterium strains. Graphic
ISSN:0008-6215
1873-426X
DOI:10.1016/j.carres.2003.05.002