Heterometallic Cluster Assembly on a Rhenium-Monocarborane Substrate

Heterometallic Cluster Assembly on a Rhenium-Monocarborane Substrate

Building butterflies: A carborane‐supported {ReIrAu2} butterfly has been assembled by stepwise addition of iridium and then gold to a rhenium‐monocarborane complex (see picture green=BH, orange=B, black=CPh). The method of preparation has considerable potential for the synthesis of other new heterop...

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Veröffentlicht in:Angewandte Chemie International Edition 2003-12, Vol.42 (46), p.5728-5730
Hauptverfasser: Du, Shaowu, Kautz, Jason A., McGrath, Thomas D., Stone, F. Gordon A.
Format: Artikel
Sprache:eng
Schlagworte:
carboranes
cluster compounds
gold
heterometallic compounds
rhenium
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Zusammenfassung:Building butterflies: A carborane‐supported {ReIrAu2} butterfly has been assembled by stepwise addition of iridium and then gold to a rhenium‐monocarborane complex (see picture green=BH, orange=B, black=CPh). The method of preparation has considerable potential for the synthesis of other new heteropolymetallic species.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200352310