Recyclable Polyurea-Microencapsulated Pd(0) Nanoparticles:  An Efficient Catalyst for Hydrogenolysis of Epoxides

Recyclable Polyurea-Microencapsulated Pd(0) Nanoparticles:  An Efficient Catalyst for Hydrogenolysis of Epoxides

Pd nanoparticles (∼2 nm in size) microencapsulated in polyurea is an efficient and recyclable catalyst for reductive ring-opening hydrogenolysis of epoxides, using either HCOOH/Et3N or H2 as a hydrogen donor.

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Veröffentlicht in:Organic letters 2003-11, Vol.5 (24), p.4665-4668
Hauptverfasser: Ley, Steven V, Mitchell, Claire, Pears, David, Ramarao, Chandrashekar, Yu, Jin-Quan, Zhou, Wuzong
Format: Artikel
Sprache:eng
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Zusammenfassung:Pd nanoparticles (∼2 nm in size) microencapsulated in polyurea is an efficient and recyclable catalyst for reductive ring-opening hydrogenolysis of epoxides, using either HCOOH/Et3N or H2 as a hydrogen donor.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol0358509