Thermodynamically controlled cyclisation reactions with double phenylsulfanyl migration

Thermodynamically controlled cyclisation reactions with double phenylsulfanyl migration

Enantiomerically enriched C2-symmetric tetrols were synthesised by a route involving a 'self-metathesis' reaction with Grubbs' second-generation ruthenium catalyst; these tetrols produced interesting bicyclic products when rearranged under acidic conditions.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2003-11 (21), p.2696-2697
Hauptverfasser: Carlisle, Julie, Fox, David J, Warren, Stuart
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Enantiomerically enriched C2-symmetric tetrols were synthesised by a route involving a 'self-metathesis' reaction with Grubbs' second-generation ruthenium catalyst; these tetrols produced interesting bicyclic products when rearranged under acidic conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/b308609g