Preparation and Characterization of N-Alkyl-Se-alkylselenocarbamates

Several N-alkyl-Se-alkylselenocarbamates were prepared. The structure was confirmed by X-ray diffraction. N-Alkyl-Se-alkylselenocarbamates showed interesting NMR spectral features in 13C and 77Se NMR. They could be explained by the equilibrium between the major s-trans and the minor s-cis forms. Thi...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Journal of organic chemistry 2002-01, Vol.67 (2), p.486-490
Hauptverfasser:	Koketsu, Mamoru, Ishida, Masaru, Takakura, Naotaka, Ishihara, Hideharu
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Noncondensed benzenic compounds Organic chemistry Preparations and properties
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Several N-alkyl-Se-alkylselenocarbamates were prepared. The structure was confirmed by X-ray diffraction. N-Alkyl-Se-alkylselenocarbamates showed interesting NMR spectral features in 13C and 77Se NMR. They could be explained by the equilibrium between the major s-trans and the minor s-cis forms. This assumption was confirmed by the theoretical calculations.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo010763k